Neutral baths are often the preferred choice for plating ceramic or plastic substrates, as there is no free cyanide in the solution that could attack and possibly damage these delicate surfaces. The use of chelating agents is essential when plating with a neutral gold solution in order to prevent the deposition of metallic impurities. Acid — An acid gold plating bath features a low … NKMcB24R15Oi Traditionally, gold has been plated from gold cyanide electrolytes, where (Au+) is ligated with cyanide (CN-). The cyanide bath is exceptionally stable with the stability constant of AuCN being 1038 [38]. However, due to concerns about safety and disposal of process waste, there is growing concern regarding the use of cyanide based processes [33]. 98CJOWYoZgf1 In acidic gold plple cyanide containing species are Au(CN)2- and HCN. The cathodic electrode reaction may be written as: Au(CN)2- +2H+ +e = Au + 2HCN. Before deposition, the concentration of free HCN in the bath is very low, approximately close to zero because of the high stability of the gold (I) cyanideplex, Au(CN)2-. Dyj6mPeDou1s Gold plating solutions, as originally configured, contained some excess of free alkali cyanide, which served as a portion of the electrolyte. This automatically established the solution pH in the cyanide is highly surface active and difficult to rinse, caused occasional staining problems as well. EVqN0bYYNuw6
Get Price